新型能源材料科研团队
课题组成员：张競方，肖志昌，赵孝先，蒙涛，李慧亮
研究方向简介：
随着能源需求日益扩大，气候和环境恶化逐渐加剧，如何拯救我们赖以生存的地球家园，已经迫在眉睫。光、电化学能源存储与转化技术是取代化石燃料，降低排放，获取高价值化学品的重要途径。其中，光、电催化剂材料是光电化学能源存储和转化的核心。
本方向主要从事锂硫电池、超级电容器、燃料电池、光电催化分解水产氢以及CO2转化、金属-空气电池等领域的研究。通过对催化剂材料的化学结构进行精确设计，从提高活性位的数量和提高活性位的本征活性两个角度出发，设计并开发高性能光电催化剂，以提高光电催化能源转化效率。将理论计算与实验相结合，加深对电催化机理的理解，为设计具有更高活性、选择性和使用寿命的光电催化剂提供理论指导。
氢气，作为目前能量密度最高的已知燃料，因其可实现二氧化碳零排放的特点，一直被认为是理想的能源载体。电解水制氢是生产高纯度氢的重要方法，通常由阴极析氢（HER)和阳极析氧（OER）两个半反应构成。而氧还原反应（ORR）和OER是燃料电池、金属-空气电池等电化学能量转换装置所包含的一对可逆电化学反应。然而，OER、HER、ORR缓慢的反应动力学与目前较低的反应可逆性，成为制约电解水制氢技术以及燃料电池发展的瓶颈。开发高效OER、HER、ORR电催化剂也是我们开展的一项重要研究工作。
科研项目：
1、国家自然科学基金青年科学基金项目，超细纳米Pt/过渡金属氮化物复合材料的可控合成及其电催化氧还原性能研究（21805069），27万元，2019/1/1-2021/12/31，主持人：张競方
2、河北省自然科学基金优秀青年基金项目，过渡金属硫属化合物异质结构的亚纳米界面调控及电催化产氧性能研究B2019204269， 20万元，2019-01 至 2021-12。主持人：张競方
3、河北省自然科学基金面上项目，介孔Na3V2(PO4)3@C复合钠离子电池正极材料的构筑及其性能研究B2019204009，10.0万元，2019年1月-2021年12月。主持人：赵孝先
4、河北省自然科学基金面上项目，基于席夫碱化学的维度可控富碳纳米材料的制备及锂离子电容器性能研究E2019204131，10.0万元，2019年1月-2021年12月。主持人：肖志昌
发表的主要论文：
1. Jingfang Zhang, Yuchen Hu, Dali Liu, Yu Yu, Bin Zhang*, Enhancing Oxygen Evolution Reaction at High Current Densities on Amorphous-Like Ni-Fe-S Ultrathin Nanosheets via Oxygen Incorporation and Electrochemical Tuning, Adv. Sci., 2017, 4, 1600343. (被Wiley新闻网MaterialsViews报道；三次进入月度论文下载排行前10名) (工程技术类一区，影响因子：9.034)
2. Kaidan Li†, Jingfang Zhang†, Rui Wu, Yifu Yu, Bin Zhang*, Anchoring CoO Domains on CoSe2 Nanobelts as Bifunctional Electrocatalysts for Overall Water Splitting in Neutral Media, Adv. Sci., 2016, 3, 1500426. (被Wiley新闻网MaterialsViews报道) (†平行一作；工程技术类一区，影响因子：9.034)
3. Jingfang Zhang, Kaidan Li, Bin Zhang*, Synthesis of Dendritic Pt-Ni-P Alloy Nanoparticles with Enhanced Electrocatalytic Properties, Chem. Commun., 2015, 51, 12012-12015. (化学类一区，影响因子：6.567)
4. Jingfang Zhang, You Xu, Bin Zhang*, Facile Synthesis of 3D Pd-P Nanoparticle Networks with Enhanced Electrocatalytic Performance towards Formic Acid Electrooxidation, Chem. Commun., 2014, 50, 13451-13453. (封底论文) (化学类二区，影响因子：6.834)
5. Jingfang Zhang, Cuibo Liu, Bin Zhang*, "Insights into Single-Atom Metal–Support Interactions in Electrocatalytic Water Splitting", Small Methods, 2019, 3, 1800481.
6. Aijing Ma, Ailiu Chang, Jingfang Zhang*, Jianzhou Gui, Dan Liu, Yifu Yu, and Bin Zhang*, "MnO2-Mediated Synthesis of Mn3O4@CaMn7O12 Core@Shell Nanorods for Electrocatalytic Oxygen Reduction Reaction", ChemElectroChem, 2019, 6, 618 – 622. 三区
7. Kong DB(#), Xiao ZC(#), Gao Y, Zhang XH, Guo RY, Huang XX, Li XL, Zhi LJ, Sp2-carbon dominant carbonaceous materials for energy conversion and storage, Mat. Sci. Eng., R 2019, 137, 1-37. (IF=24.480)
8. Zhichang Xiao, Xiaoxiong Huang, Kun Zhao, Qi Song, Ruiying Guo, Xinghao Zhang, Shanke Zhou, Debin Kong,* Manfred Wagner, Klaus Müllen, and Linjie Zhi*，Band Structure Engineering of Schiff-Base Microporous Organic Polymers for Enhanced Visible-Light Photocatalytic Performance, Small, 2019, 15, 1900244. 一区
9. Zhichang Xiao, Xiaohui Xu, Debin Kong, Jiaxu Liang, Shanke Zhou, Xiaoxiong Huang, Qi Yang and Linjie Zhi, Chemical tailoring of one-dimensional polypyrene nanocapsules at a molecular level: towards ideal sulfur hosts for high-performance Li-S batteries, Journal of Materials Chemistry A, 2019，7（5），2009-2014. 一区 第二单位
10. Yang Gao, Zhichang Xiao, Debin Kong, Rashid Iqbal, Quan-Hong Yang, Linjie Zhi, N,P co-doped hollow carbon nanofiber membranes with superior mass transfer property for trifunctional metal-free electrocatalysis, Nano Energy, 2019，64， 103879. 一区
11. Jiaxu Liang, Zhichang Xiao, Yang Gao, Xiaohui Xu, Debin Kong, Manfred Wagner Linjie Zhi, Ionothermal strategy towards template-free hierarchical porous carbons for supercapacitive energy storage, Carbon, 2019，143，487-493. 一区
12. Debin Kong, Zhichang Xiao, Yang Gao, Xinghao Zhang, Ruiying Guo, Xiaoxiong Huang, Xianglong Li, Linjie Zhi, Sp(2)-carbon dominant carbonaceous materials for energy conversion and storage. Materials Science and Engineering: R: Reports 2019，137，1-37. 一区
13. Xiao ZC, Kong DB, Song Q, Zhou SK, Zhang YB, Badshah A, Liang JX, Zhi LJ, A facile Schiff base chemical approach: towards molecular-scale engineering of n-c interface for high performance lithium-sulfur batteries, Nano Energy 2018, 46, 365-371. (IF= 13.120)
14. Xiao ZC, Song Q, Guo RY, Kong DB, Zhou SK, Huang XX, Rashid I, Zhi LJ, Nitrogen-enriched carbon/CNT composites based on Schiff-base networks: ultrahigh N content and enhanced lithium storage properties, Small 2018, 14, e1703569. (IF= 9.598)
15. Xiao ZC, Kong DB, Liang JX, Wang B, Rashid I, Yang QH, Zhi LJ, Structure controllable carbon matrix derived from benzene-constructed porous organic polymers for high-performance Li-S batteries, Carbon 2017, 116, 633-639. (IF=7.082)
16. Xiao ZC, Han JW, Xiao J, Song Q, Zhang XH, Kong DB, Yang Q-H, Zhi LJ, A facile and processable integration strategy towards Schiff-base polymer derived carbonaceous materials with high lithium storage performance, Nanoscale 2018, 10, 10351-10356. (IF=7.233)
17. Songwei Gao, Nü Wang, Shuai Li, Dianming Li, Zhimin Cui, Guichu Yue, Jingchong Liu, Xiaoxian Zhao*, Lei Jiang, Yong Zhao*, Multi-wall Sn/SnO2@Carbon Hollow Nanofibers Anode Material for High-Rate and Long-Life Lithium-Ion Batteries, Angewandte Chemie - International Edition, Angew. Chem. Int. Ed. 2020, 59, 2465-2472. 一区
18. Zhao X, Yu R, Tang H, Mao D, Qi J, Wang B, Zhang Y, Zhao H, Hu W, Wang D. Formation of Septuple-Shelled (Co2/3Mn1/3)(Co5/6Mn1/6)2O4 Hollow Spheres as Electrode Material for Alkaline Rechargeable Battery[J]. Advanced Materials, 2017, 29(34).
19. Zhao X, Wang J, Yu R, et al. Construction of multishelled binary metal oxides via coabsorption of positive and negative ions as a superior cathode for sodium-ion batteries[J]. Journal of the American Chemical Society, 2018, 140(49): 17114-17119.
20. Jiao C, Wang Z, Zhao X, Wang H, Wang J, Yu R B, Wang, D. Triple-Shelled Manganese-Cobalt Oxide Hollow Dodecahedra with Highly Enhanced Performance for Alkaline Rechargeable Battery[J]. Angew. Chem. Int. Ed. 10.1002/anie.201811683.
21. Zhao X, Li J, Zhang Y, et al. Preparation of nanosized anatase TiO2-coated illite composite pigments by Ti(SO4)2 hydrolysis[J]. Powder Technology, 2015, 271: 262-269.
22. Zhao X, Li J, Liu Y, et al. Preparation and mechanism of TiO2-coated illite composite pigments[J]. Dyes and Pigments, 2014, 108: 84-92.
23.Tao Meng, Jinwen Qin, Zhen Yang, Lirong Zheng, Minhua Cao*. Significantly improved Li-ion diffusion kinetics and reversibility of Li2O in MoO2 anode: the effects of oxygen vacancy-induced local charge distribution and metal catalysis on lithium storage. J. Mater. Chem. A, 2019, 7, 17570.
24. Tao Meng, Jinwen Qin, Dan Xu, Minhua Cao*. Atomic heterointerface-induced local charge distribution and enhanced water adsorption behavior in cobalt phosphide electrocatalyst for self-powered highly efficient overall water wplitting. ACS Appl. Mater. Interfaces, 2019, 11, 9023.
25. Tao Meng,# Yi-Ning Hao,# Jinwen Qin, Minhua Cao*. Interface-engineering-induced electric field effect and atomic disorder in cobalt selenide for high-rate and large-capacity lithium storage. ACS Sustainable Chem. Eng. 2019, 7, 4657.
26. Tao Meng, Yi-Ning Hao, Lirong Zheng, Minhua Cao*. Organophosphoric acid-derived CoP quantum dots@S,N-codoped graphite carbon as a trifunctional electrocatalyst for overall water splitting and Zn-air batteries. Nanoscale, 2018, 10, 14613.
27. Tao Meng, Minhua Cao*. Transition metal carbide complex architectures for energy-related applications. Chem. Eur. J. 2018, 24, 16716.
28. Tao Meng, Jinwen Qin, Shuguang Wang, Di Zhao, Baoguang Mao, Minhua Cao*. In situ coupling of Co0.85 Se and N-doped carbon via one-step selenization of metal-organic frameworks as a trifunctional catalyst for overall water splitting and Zn-air batteries. J. Mater. Chem. A, 2017, 5, 7001.
29. Tao Meng, Lirong Zheng, Jinwen Qin, Di Zhao, Minhua Cao*. A three-dimensional hierarchically porous Mo2C architecture: salt-template synthesis of a robust electrocatalyst and anode material towards the hydrogen evolution reaction and lithium storage. J. Mater. Chem. A, 2017, 5, 20228.
30. Tao Meng, Qianqian Xu, Zhihong Wang, Yintao Li, Zemin Gao, Xiangying Xing, Tiezhen Ren*. Co3O4 nanorods with self-assembled nanoparticles in queue for supercapacitor. Electrochimica Acta, 2015, 180,104.
31. Tao Meng, Qianqian Xu, Yintao Li, Xiangying Xing, Chunsheng Li, Tie-Zhen Ren*. Graphene supported ni-based nanocomposites as electrode materials with high capacitance. Electrochimica Acta, 2015, 155, 69
32. Tao Meng, Qianqian Xu, Yintao Li, Jianli Chang, Tiezhen Ren*, Zhongyong Yuan*. Nickle nanoparticles highly dispersed on reduced graphene oxide for ammonia decomposition to hydrogen. J. Ind. Eng. Chem., 2015, 32 373.
33. Tao Meng, Peipei Ma, Jianli Chang, Zhihong Wang, Tiezhen Ren*. The electrochemical capacitive behaviors of NiO nanoparticles. Electrochimica Acta, 2014, 125, 586.
34. Huiliang Li, Fengping Li, Zeyan Wang, Yachen Jiao, Yuanyuan Liu, Peng Wang, Xiaoyang Zhang, Xiaoyan Qin, Ying Dai, Baibiao Huang, Fabrication of carbon bridged g-C3N4 through supramolecular self-assembly for enhanced photocatalytic hydrogen evolution, Applied Catalysis B: Environmental, 2018, 229, 114-120. IF:14.229，一区，TOP期刊
35. Huiliang Li, Cui Jin, Zeyan Wang, Yuanyuan Liu, Peng Wang, Zhaoke Zheng, M.-H. Whangbo, Liangzhi Kou, Yingjie Li, Ying Dai, Baibiao Huang, Effect of the intra- and inter-triazine N-vacancies on the photocatalytic hydrogen evolution of graphitic carbon nitride, Chemical Engineering Journal, 2019,369,263-271. IF:8.355, 一区， TOP期刊
36. Huiliang Li, Bo Zhang, Zeyan Wang, Peng Wang, Yuanyuan Liu, Xiaoyang Zhang, Xiaoyan Qin, Ying Dai, M.-H. Whangbo, Baibiao Huang, Endotaxial Growth of [100]-Oriented TaON Films on LiTaO3 Single Crystals for Enhanced Photoelectrochemical Water Splitting, Solar RRL, 2018, 2, 1700243.
37. Huiliang Li, Huining Huang, Zeyan Wang, Zhaoke Zheng, Peng Wang, Yuanyuan Liu, Xiaoyang Zhang, Xiaoyan Qin, Ying Dai, Yingjie Li, Huiling Zou, Baibiao Huang, In situ extract nucleate sites for the growth of free-standing carbon nitride films on various substrates, Catalysis Today, 2019, DOI: 10.1016/j.cattod.2019.02.022. IF:4.888, 二区，TOP期刊
